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The solo from Another Day is another awesome one to work one. The one alternate picking lick is a little intense and is something to work towards, but the rest is very melodic and challenging.
If he's getting into Dream Theater, maybe a few Liquid Tension Experiment songs will be cool to work on as well. The first that comes to mind is Biaxident, as it's really not that difficult to play and is an awesome song overall.
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